亚临界技术处理后的牡蛎壳吸附重金属的性能评价

    Evaluation on the Adsorption of Heavy Metals by Oyster Shell Treated with Subcritical Technology

    • 摘要: 通过研究亚临界技术处理后牡蛎壳对重金属吸附性能的影响,探究牡蛎壳制备土壤修复剂的可行性。牡蛎壳经过亚临界水解处理后对重金属离子具有较强的吸附性能,通过设置不同温度和压力处理、相同温度不同处理、牡蛎壳粉不同添加量,不同重金属初始浓度等试验开展研究,利用电感耦合等离子体发射光谱仪进行元素分析检测,结果表明:牡蛎壳粉对重金属Cd、Pb、Cr、Zn、Cu的吸附性能符合准二级动力学方程和Langmuir等温模型。利用亚临界制备的牡蛎壳粉去除Cd最佳添加量为5~10 g·L-1,去除Pb、Cr、Zn、Cu的最佳添加量为1~5 g·L-1;牡蛎壳粉末对重金属Cd、Pb、Cr、Zn、Cu的去除率最高可达到95.99%、98.68%、98.67%、93.22%和80.51%。

       

      Abstract: In order to explore the feasibility of preparing the repairing additive of soil from oyster shells, the effects of oyster shells treated with the subcritical technology on the adsorption of heavy metal were studied. The oyster shells had strong adsorption for the heavy metal ions after the treatment of subcritical hydrolysis. The experiments were carried out by setting different temperature and pressure treatments, different treatments at the same temperature, different additive amounts of oyster shell powder, and different initial concentrations of heavy metals. And then the analysis and detection on the elements were conducted by using the inductively coupled plasma atomic emission spectrometer (ICP-AES). The results showed that the adsorption of the oyster shell powder for the heavy metals such as Cd, Pb, Cr, Zn and Cu was in accordance with the quasi-second-order kinetic equation and Langmuir isothermal model. The optimal additive amount of oyster shell powder to remove Cd which prepared by subcritical technology was 5-10 g·L-1, and the optimal additive amount of oyster shell powder to remove Pb, Cr, Zn and Cu was 1-5 g·L-1. The removal rates of Cd, Pb, Cr, Zn and Cu by the oyster shell powder could reach 95.99%, 98.68%, 98.67%, 93.22% and 80.51%, respectively.

       

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