7种土壤调理剂对铅汞复合污染稻田土壤的钝化效应探讨

    Study on the Passivation Effect of Seven Soil Conditioners on Paddy Soil Contaminated by Lead and Mercury

    • 摘要: 为筛选适于中轻度铅汞(Pb-Hg)复合污染稻田治理的钝化材料,以Pb-Hg复合污染稻田土壤为研究对象,选用目前市场上应用效果较好的7种土壤调理剂,研究不同土壤调理剂对污染稻田土壤pH、有机质、阳离子交换量(CEC)、重金属有效态铅(DTPA-Pb)含量、糙米Pb和Hg含量以及水稻产量的影响。结果表明:7种土壤调理剂均能提高土壤pH值,其中楚戈提升幅度最大(13.29%);维地康、诺地康、铁基生物炭、天象一号、楚戈能显著增加土壤CEC,其中维地康增幅最大(10.99%);诺地康和铁基生物炭能显著提高土壤有机质;除铁基生物炭外,其他土壤调理剂均显著降低土壤DTPA-Pb含量;7种土壤调理剂均能显著降低糙米Pb、Hg含量,显著提高水稻产量,产量增幅为4.58%~21.69%,其中铁基生物炭增产效果最好(1 737.04 kg·hm-2)。综上,铁基生物炭通过增加土壤有机质含量,提升土壤保肥、保水、缓冲能力,能够降低土壤Pb有效性及糙米Pb和Hg含量、提高水稻产量效果最好,适用于土壤保肥、保水能力差、Pb-Hg复合污染稻田土壤治理。

       

      Abstract: In order to screen the passivation materials suitable for the treatment of the paddy fields with moderate and mild Pb-Hg compound pollution, the soil of paddy fields with Pb-Hg compound pollution was taken as the research object, and seven kinds of soil conditioners with good application effects on the market were selected to study the effects of different soil conditioners on the soil pH, organic matter, cation exchange capacity (CEC), heavy metal available lead (DTPA-Pb) content, Pb and Hg content in brown rice and the rice yield. The results showed that all the seven soil conditioners could increase the soil pH value, among which Chuge increased the most (being 13.29%). Weidikang, Nuodikang, the iron-based biochar, Tianxiang No.1 and Chuge could significantly increase the soil CEC value, among which Weidikang had the largest increase (being 10.99%). Nuodikang and the iron-based biochar could significantly increase the soil organic matter; Except for the iron-based biochar, the other soil conditioners all significantly reduced the DTPA-Pb content in soil. All the seven soil conditioners could significantly reduce the contents of Pb and Hg in brown rice, and significantly increase the rice yield, with an increase of 4.58% to 21.69%, among which the iron-based biochar had the best yield-increasing effect (being 1 737.04 kg·hm-2). In summary, the iron-based biochar had the best effect on reducing the availability of Pb in soil and the content of Pb and Hg in brown rice, and improving the yield of rice by increasing the content of soil organic matter, improving the soil fertilizer retention, water retention and buffering capacity. Therefore, it was suitable for the soil treatment of paddy fields with poor soil fertilizer retention, water retention capacity and Pb-Hg compound pollution.

       

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