无机盐、水质和pH值对高效氯氟氰菊酯微乳剂物理稳定性的影响

    Effect of Inorganic Salts, Water Quality, and pH Value on the Physical Stability of Lambda-cyhalothrin Microemulsion

    • 摘要: 微乳剂是一种水基性的环保农药剂型,稳定性是其关键质量指标。为微乳剂的开发与实际应用提供参考,以微乳剂的浊点、乳液稳定性、冷贮和热贮稳定性、表面张力等为性能指标,研究了无机盐、水质和pH值对高效氯氟氰菊酯微乳剂物理稳定性的影响。结果表明:随着NaCl、KCl、CaCl2、MgCl2、KNO3、KI等6种无机盐质量分数的提高,微乳剂的浊点逐渐下降,其中下降幅度最大的是KCl,最小的是KI;在一定质量分数范围内,添加无机盐对微乳剂的外观、乳液稳定性、冷贮稳定性和表面张力影响不大,但NaCl、KCl和CaCl2对制剂的热贮稳定性具有一定影响;水质对微乳剂的浊点具有显著影响,以去离子水制备的微乳剂浊点最高,随着水的硬度增加,浊点逐渐降低,但水质对制剂的外观、乳液稳定性、冷贮稳定性、热贮稳定性、表面张力无明显影响;pH值对微乳剂的物理稳定性影响不大。

       

      Abstract: Microemulsion is a water-based environmentally-friendly pesticide formulation, and stability is its key quality indicator. The effects of inorganic salts, water quality and pH value on the physical stability of lambda-cyhalothrin microemulsion were studied by using the cloud point, emulsion stability, cold storage and thermal storage stability and surface tension of the microemulsion as the performance indexes, aiming to provide reference for the preparation and practical application of microemulsion. The results showed that with the increase in mass fractions of six inorganic salts (NaCl, KCl, CaCl2, MgCl2, KNO3, and KI), the cloud point of lambda-cyhalothrin microemulsion gradually decreased. Among them, KCl caused the largest reduction in the cloud point, while KI resulted in the smallest decrease. Within a certain mass fraction range, the addition of inorganic salts had little effect on the appearance, emulsion stability, cold storage stability, and surface tension of lambda-cyhalothrin microemulsion. However, NaCl, KCl, and CaCl2 had a certain effect on the thermal storage stability of the preparation. The water quality had a significant effect on the cloud point of the lambda-cyhalothrin microemulsion. The microemulsion prepared with deionized water exhibited the highest cloud point, which gradually decreased as the hardness of the water increased. However, water quality had no noticeable effect on the appearance, emulsion stability, cold storage and thermal storage stability, and surface tension of the preparation. The pH value had little effect on the physical stability of lambda-cyhalothrin microemulsion.

       

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